Chemistry – 306 Syllabus for Class 12


Unit I: Solid State

  • Classification of solids based on different binding forces: molecular, ionic, covalent, and metallic solids.
  • Amorphous and crystalline solids (elementary idea).
  • Unit cell in two-dimensional and three-dimensional lattices.
  • Calculation of density of unit cell, packing in solids, packing efficiency, voids.
  • Number of atoms per unit cell in a cubic unit cell, point defects.
  • Electrical and magnetic properties.
  • Band theory of metals, conductors, semiconductors, and insulators, and n and p-type semiconductors.

Unit II: Solutions

  • Types of solutions.
  • Expression of concentration of solutions of solids in liquids.
  • Solubility of gases in liquids, solid solutions.
  • Colligative properties: relative lowering of vapor pressure, Raoult’s law, elevation of B.P., depression of freezing point, osmotic pressure.
  • Determination of molecular masses using colligative properties.
  • Abnormal molecular mass, Van’t Hoff factor.

Unit III: Electrochemistry

  • Redox reactions; conductance in electrolytic solutions.
  • Specific and molar conductivity variations with concentration.
  • Kohlrausch’s Law.
  • Electrolysis and laws of electrolysis (elementary idea).
  • Dry cell – electrolytic cells and Galvanic cells; lead accumulator.
  • EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells.
  • Relation between Gibbs energy change and EMF of a cell.
  • Fuel cells, corrosion.

Unit IV: Chemical Kinetics

  • Rate of a reaction (average and instantaneous).
  • Factors affecting rates of reaction: concentration, temperature, catalyst.
  • Order and molecularity of a reaction.
  • Rate law and specific rate constant.
  • Integrated rate equations, and half-life (only for zero and first-order reactions).
  • Concept of collision theory (elementary idea, no mathematical treatment).
  • Activation energy, Arrhenius equation.

Unit V: Surface Chemistry

  • Adsorption – physisorption and chemisorption.
  • Factors affecting adsorption of gases on solids.
  • Catalysis: homogeneous and heterogeneous, activity and selectivity.
  • Enzyme catalysis.
  • Colloidal state: distinction between true solutions, colloids, and suspensions.
  • Lyophilic, lyophobic multimolecular, and macromolecular colloids.
  • Properties of colloids: Tyndall effect, Brownian movement, electrophoresis, coagulation.
  • Emulsions – types of emulsions.

Unit VI: General Principles and Processes of Isolation of Elements

  • Principles and methods of extraction: concentration, oxidation, reduction, electrolytic method, and refining.
  • Occurrence and principles of extraction of aluminum, copper, zinc, and iron.

Unit VII: p-Block Elements

  • Group 15 elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties.
    • Nitrogen: preparation, properties, and uses.
    • Compounds of nitrogen: preparation and properties of ammonia and nitric acid, oxides of nitrogen (structure only).
    • Phosphorus: allotropic forms; compounds of phosphorus: preparation and properties of phosphine, halides (PCl₃, PCl₅), and oxoacids (elementary idea only).
  • Group 16 elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties.
    • Dioxygen: preparation, properties, and uses.
    • Classification of oxides; ozone.
    • Sulfur: allotropic forms; compounds of sulfur: preparation, properties, and uses of sulfur dioxide, sulfuric acid: industrial process of manufacture, properties and uses, oxoacids of sulfur (structures only).
  • Group 17 elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties.
    • Compounds of halogens: preparation, properties, and uses of chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens (structures only).
  • Group 18 elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.

Unit VIII: d and f Block Elements

  • General introduction, electronic configuration, occurrence and characteristics of transition metals.
  • General trends in properties of the first-row transition metals: metallic character, ionization enthalpy, oxidation states, ionic radii, color, catalytic property, magnetic properties, interstitial compounds, alloy formation.
  • Preparation and properties of K₂Cr₂O₇ and KMnO₄.
  • Lanthanoids: electronic configuration, oxidation states, chemical reactivity, and lanthanoid contraction and its consequences.
  • Actinoids: Electronic configuration, oxidation states, and comparison with lanthanoids.

Unit IX: Coordination Compounds

  • Coordination compounds: Introduction, ligands, coordination number, color, magnetic properties, and shapes.
  • IUPAC nomenclature of mononuclear coordination compounds, bonding, Werner’s theory, VBT, CFT.
  • Isomerism (structural and stereo).
  • Importance of coordination compounds in qualitative analysis, extraction of metals, and biological systems.

Unit X: Haloalkanes and Haloarenes

  • Haloalkanes: Nomenclature, nature of C-X bond, physical and chemical properties, mechanism of substitution reactions, optical rotation.
  • Haloarenes: Nature of C-X bond, substitution reactions (directive influence of halogen for monosubstituted compounds only).
  • Uses and environmental effects of: dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT.

Unit XI: Alcohols, Phenols, and Ethers

  • Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only); identification of primary, secondary, and tertiary alcohols; mechanism of dehydration, uses, with special reference to methanol and ethanol.
  • Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophilic substitution reactions, uses of phenols.
  • Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.

Unit XII: Aldehydes, Ketones, and Carboxylic Acids

  • Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties, mechanism of nucleophilic addition, the reactivity of alpha hydrogen in aldehydes; uses.
  • Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.

Unit XIII: Organic Compounds Containing Nitrogen

  • Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary, secondary, and tertiary amines.
  • Cyanides and Isocyanides – will be mentioned at relevant places in context.
  • Diazonium salts: Preparation, chemical reactions, and importance in synthetic organic chemistry.

Unit XIV: Biomolecules

  • Carbohydrates: Classification (aldoses and ketoses), monosaccharides (glucose and fructose), D-L configuration, oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen): importance.
  • Proteins: Elementary idea of α-amino acids, peptide bond, polypeptides, proteins, primary structure, secondary structure, tertiary structure, and quaternary structure (qualitative idea only), denaturation of proteins; enzymes.
  • Hormones: Elementary idea (excluding structure).
  • Vitamins: Classification and functions.
  • Nucleic Acids: DNA and RNA.

Unit XV: Polymers

  • Classification – Natural and synthetic, methods of polymerization (addition and condensation), copolymerization.
  • Some important polymers: natural and synthetic like polythene, nylon, polyesters, bakelite, rubber.
  • Biodegradable and non-biodegradable polymers.

Unit XVI: Chemistry in Everyday Life

  1. Chemicals in Medicines: Analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines.
  2. Chemicals in Food: Preservatives, artificial sweetening agents, elementary idea of antioxidants.
  3. Cleansing Agents: Soaps and detergents, cleansing action.

 

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Chemistry – 306 Syllabus for Class 12